When to seek God in prayer

Psalm 5:3
My voice shalt thou hear in the morning, O LORD; in the morning will I direct my prayer unto thee, and will look up.

David says God will hear him in the morning.
 

Psalm 63:1
O God, thou art my God; early will I seek thee: my soul thirsteth for thee, my flesh longeth for thee in a dry and thirsty land, where no water is;

David says again that early will he seek God.

Daniel prayed 3 times a day (Daniel 6:10) and Paul prayed unceasingly (2 Timothy 1:3), but one thing is for sure, we are to seek God out in prayer first thing in the morning because we do not know what else the day is going to bring. The day might bring many opportunities to commune with him, and the day may bring one hectic emergency after another. If we sought out the Lord first, we have that communion with him to help us through the day.